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2025-04-15
Outcompeting Thermodynamics: Ion-Pairing and Coulombic Interactions to Trigger Perfluoroacetate Intra-Ionic Photooxidation for Perfluoroalkylation Reactions
Trifluoromethylation is a key transformation in drug and agrochemical synthesis, yet current reagents often suffer from high cost, low atom economy, and low scalability. [Discover more...]
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2025-03-25
Two Birds, One Stone: Microsecond Dark Excited-State Lifetime and Large Cage Escape Yield Afforded by an Iron−Anthracene Molecular Dyad
Iron photosensitizers represent a holy grail in photochemistry, but their widespread implementation is limited by their short excited-state lifetimes and poor cage escape yields.
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2025-03-10
High-Performance Ionogels from Dynamic Polyrotaxane-Based Networks
The swelling of a polymer matrix by ionic liquids and additional lithium salts may lead to the
formation of ionogel electrolytes. However, the introduction of additional ions usually results in a decreased lithium-ion transference number, because of the trapping of the lithium ions in clusters and polymer-ion complexes. [Discover more...]
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2025-01-13
Neuromorphic weighted sums with magnetic skyrmions
Integrating magnetic skyrmions into neuromorphic computing could help improve hardware efficiency and computational power. However, developing a scalable implementation of the weighted sum of neuron signals - a core operation in neural networks - has remained a challenge.
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2024-09-20
Factors Controlling Cage Escape Yields of Closed- and Open-Shell Metal Complexes in Bimolecular Photoinduced Electron Transfer
The cage escape yield, i.e., the separation of the geminate radical pair formed immediately after bimolecular excited-state electron transfer, was studied in 11 solvents using six Fe(III), Ru(II), and Ir(III) photosensitizers and tri-p-tolylamine as the electron donor. [Discover more...]
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